I'm having some problems with this.
I know that lower bound will be $\dfrac{1}{2}$. Should I just find $m,n$ for which $\dfrac{m\cdot n}{m+n} \lt \dfrac{1}{2} + \epsilon $? Also I'm not sure how to prove that it's the best possible lower bound.
Also I presume that there isn't any upper bound, thus it goes to infinity, but I have problems coming up with the proof.
Thank you for any hints.
The number $\dfrac12$ is a lower bound because, for each $m,n\in\mathbb N$, you have$$\frac{mn}{m+n}\geqslant\frac12.$$That's so because\begin{align}\frac{mn}{m+n}\geqslant\frac12&\iff2mn\geqslant m+n\\&\iff2mn-m-n\geqslant0\\&\iff mn+mn-m-n+1\geqslant1\\&\iff mn+(m-1)(n-1)\geqslant1,\end{align}which is true. On the other hand $\dfrac{1\times1}{1+1}=\dfrac12$ and therefore $\dfrac12$ is the greatest lower bound.
On the other hand, $\lim_{n\to\infty}\dfrac{n^2}{2n}=\infty$, and therefore your set has no upper bound.