As an extension of my earlier question,
It is required to find f(x) with following properties,
$$ f(0) = 0 \hspace{1cm}f(1) = 1 \\ f'(0) = 0 \hspace{1cm}f'(1) = 0 \\ f''(0) = 0 \hspace{1cm}f''(1) = 0 \\ f'''(0) = 0 \hspace{1cm}f'''(1) = 0 \\ \dots \\ f^{(n)}(0) = 0 \hspace{1cm}f^{(n)}(1) = 0 \\ $$
and most important condition being $f'(\xi) \ge = 0 \hspace{.5cm}\forall \xi \in (0,1)$. Here prime denotes derivative of the function.
I have a solution for n = 1 and n= 2 as follows respectively(I don't assume that they are unique), \begin{eqnarray} f_1(x) &=& \frac{1}{2} \left[1- \cos(\pi x)\right] \\ f_2(x) &=& x - \frac{\sin(2\pi x)}{2\pi} \end{eqnarray}
With graphs as follwing,

It is clear from the graph that with increasing n, the solution would approach step function with jump at $x = 0.5$. I will be happy if someone can point out solution for n = 3 or higher degrees. Thanks for the attention
Instead of trig functions, how about monomials? If you want $k$ derivatives to vanish, take $$\begin {cases} f(x)=2^kx^{k+1} &0\le x \le \frac 12\\1-2^k(1-x)^{k+1} & \frac 12 \lt x \le 1 \end {cases}$$ It is continuous, but the derivatives are not. It looks like a step function as you suggested, more so as $k$ increases. The first derivative is even continuous.
The classic example of a function with all derivatives zero at $x=0$ is $\exp(\frac {-1}x)$ As you take derivatives you multiply the function by various polynomials in $\frac 1x$, but the exponential goes to zero faster as you approach zero. Once you have that, you can do many things with it. The easiest way to get both ends is $$f(x)=\begin {cases} 0& x=0 \\\exp\left(\frac {-1}x\right) & 0 \lt x \le\frac 14\\\exp (-4)+(2-4\exp(-4))(x-\frac 14)& \frac 14 \lt x \lt \frac 34\\1- \exp\left(\frac {-1}{1-x}\right)& \frac 34 \le x \lt 1 \\1& x=1\end{cases}$$ This is continuous, but the derivatives are not (at $\frac 14, \frac 34$). With some more work, you can make all the derivatives continuous as well.