The exact question:
Let $$ \Large S_n = \sum_{\stackrel{a_1, a_2, \ldots , a_n > 0}{(a_1, a_2, \ldots, a_n) \text{ are all distinct}}} \dfrac1{2^{a_1 + a_2 + \cdots + a_n}} $$ It's trivial that $S_1 = 1$ and $S_2 = \frac23$. Can we find a general form of $S_n ?$
Background/Attempt:
I was trying to compute $ \sum \limits_{\stackrel{i,j,k>0}{i \ne j, i \ne k , j \ne k}} \dfrac1{2^{i+j+k}} $, which brought me to hypergeometricx' answer here.
Using their exact notations, we can get:
$$ \sum \limits_{\stackrel{i,j,k>0}{i \ne j, i \ne k , j \ne k}} \dfrac1{2^{i+j+k}} = \displaystyle \left[ \sum_{i,j,k>0 } - \left( \sum_{\stackrel{i,j,k>0 }{i=j \ne k }} + \sum_{\stackrel{i,j,k>0 }{i\ne j=k }} \right) + \sum_{\stackrel{i,j,k>0 }{i=j=k }} \right] \dfrac1{2^{i+j+k}} = 1^3 - (\tfrac13 + \tfrac13) + \tfrac17 = \frac27$$
Equivalently,
$$ S_3 = \left( \sum_{i>0} \dfrac1{2^i} \right )^3 - {\color{red}{3}} \left( \sum_{i>0} \dfrac1{2^{2i}} \right) \left( \sum_{i>0} \dfrac1{2^{i}} \right) + {\color{red}{2}} \left( \sum_{i>0} \dfrac1{2^{3i}} \right) = \dfrac27 $$
Now, what got me interested is how can we decipher the coefficients colored in red. So I drew a Venn Diagram, and via inclusion-exclusion principle:

Moving forward, I tried to evaluate $S_4$ in the same manner.
However, I'm unable to decipher the following red coefficients:
$$ \dfrac8{105} \stackrel{?}{=} S_4\stackrel{?}{=} \underbrace{\left( \sum_{i>0} \dfrac1{2^i} \right )^4 }_{=\, 1} - {\color{red}{6}} \left( \sum_{i>0} \dfrac1{2^{3i}} \right) \left( \sum_{i>0} \dfrac1{2^{i}} \right) + {\color{red}{3}} \left( \sum_{i>0} \dfrac1{2^{2i}} \right) ^2 - {\color{red}{6}} \left( \sum_{i>0} \dfrac1{2^{4i}} \right) $$
Let alone
$$ \dfrac8{651} \stackrel{?}{=} S_5\stackrel{?}{=} \underbrace{\left( \sum_{i>0} \dfrac1{2^i} \right )^5 }_{=\, 1} - {\color{red}{10}} \left( \sum_{i>0} \dfrac1{2^{4i}} \right) \left( \sum_{i>0} \dfrac1{2^{i}} \right) + {\color{red}{19}} \left( \sum_{i>0} \dfrac1{2^{3i}} \right)\left( \sum_{i>0} \dfrac1{2^{2i}} \right) - {\color{red}{38}} \left( \sum_{i>0} \dfrac1{2^{5i}} \right) $$
I conjecture that, should this pattern continue
$$ S_n = 1 - { \color{red}{b_1}} \left( \sum_{j>0} \dfrac1{2^{(n-1)i}}\right) \left( \sum_{j>0} \dfrac1{2^{1i}} \right) + { \color{red}{b_2}} \left( \sum_{j>0} \dfrac1{2^{(n-2)i}} \right) \left( \sum_{j>0} \dfrac1{2^{2i}} \right) - { \color{red}{b_3}} \left( \sum_{j>0} \dfrac1{2^{(n-3)i}} \right) \left( \sum_{j>0} \dfrac1{2^{3i}} \right) + \cdots \pm { \color{red}{b_n}} \left( \sum_{j>0} \dfrac1{2^{1i}} \right) \left( \sum_{j>0} \dfrac1{2^{(n-1) i}} \right) \mp { \color{red}{b_n}} \left( \sum_{j>0} \dfrac1{2^{n i}} \right) $$
And since $ \sum \limits_{j>0} \frac1{2^{k \cdot j}} = \frac1{2^k - 1}$. The equation above is equivalent to:
$$ \begin{array} { r c l } S_n &=& 1 - \dfrac { \color{red}{b_1}} { (2^{n-1} - 1) (2^1 - 1)} + \dfrac { \color{red}{b_2}} { (2^{n-2} - 1) (2^2 - 1)} - \dfrac { \color{red}{b_3}} { (2^{n-3} - 1) (2^3 - 1)} + \cdots \pm \dfrac { \color{red}{b_n}} { (2^1 - 1) (2^{n-1} - 1)} \mp \dfrac { \color{red}{b_n}} { 2^{n} - 1} \\ \phantom0 \\ &=&1 + \left( \sum \limits_{k=1}^{n-1} \dfrac { (-1)^k \cdot \color{red}{b_k}} { (2^{n-k} - 1) (2^k - 1)} \right) + \dfrac { (-1)^n \cdot \color{red}{b_n}} { 2^n - 1} \end{array} $$
I suspect that $ {\color{red}{b_1}} = \binom n2 $. But I got nothing to go from here.
Restrict our attention to the case where $ a_ 1 < a_2 < a_3 \ldots $. For each instance, there are $n!$ such terms that we want to sum, so we'd have to multiply the summation by $n!$.
Use the substitution: $a_1 = x_1,$ $a_2 = a_1 + x_2 = x_1 + x_2,$ $a_3 = a_2 + x_3 = x_1 + x_2 +x_3 , \ldots,$ where $ x_ i \geq 1$, with no further restrictions.
This gives us $ \sum a_i = n x_ 1 + (n-1) x_2 + (n-2) x_3 + \ldots + x_n = \sum_{i=1}^n (n+1 - i) x_i$, and thus
$$ \sum \frac{1}{ 2^ {\sum a_i }} = \sum_{ x_i} \frac{1}{ 2^{ \sum_{i=1}^n (n+1 - i) x_i }} \\ = \prod_{i=1}^n \sum_{x_i} \frac{1}{2^{(n+1 - i)x_i}} \\ = \prod_{i=1}^n \frac{1}{2^{n+1-i} - 1 } \\ = \prod_{j=1}^n \frac{1}{ 2^j - 1 }$$
Hence, the summation has value $ n! \prod_{j=1}^n \frac{1}{ 2^j - 1 }$.