Given a matrix $A \in \mathbb{R}^{N \times N}$ where there is a row (say the $i$-th row) such that
$$a_{ij} = \delta_{ij}b ~~~~\forall j \in \{1, \ldots, N\}$$
where $$\delta_{ij} = \left\{ \begin{array}{ll}0 & i \neq j \\ 1 & i = j\end{array}\right.$$
From Gershgorin theorem, we know that there is a degenerate circle which coincides with the point $b$ in $\mathbb{C}$. Then, can we assert that this matrix has at least one eigenvalue equal to $b$?
CORRECTION
$A$ is not necessarily diagonal. $A$ has one row, say the $i$-th, such that
$$a_{ij} = \delta_{ij}b ~~~~\forall j \in \{1, \ldots, N\}$$
The way you described it, $A=b I$ where $b\in\mathbb R$ and $I$ is the identity matrix... This means all eigenvalues of $A$ equal $b$.
Edit: after you edited the question, you say you have one ($j$-th) row which has $a_{jj}=b$ and $a_{ij}=0$ for $i\neq j$. In that case, you can still claim that one eigenvalue will equal to $b$, since the determinant of $A-\lambda I$ will be $(b-\lambda)\cdot p(\lambda)$ for some polynomial $p$.