I understand that the group of automorphisms of $\mathbb{Q}$ (as a group) is isomorphic to $\mathbb{Q}^{\times}$.
I am wondering what the group of automorphisms of $\mathbb{R}$ (as an additive group) is.
I think this is isomorphic to $\mathbb{R}^\times$, but I don't know how to prove it. My idea is that (just as with $\mathbb{Q}$) an isomorphism $\phi: \mathbb{R} \to \mathbb{R}$ must satisfy $$ \phi\left( \frac{n}{m}\right) = \frac{n}{m}\phi(1). $$ But what should I do about the non-rational real numbers?
No, it's much, much larger. Assuming the axiom of choice, $\mathbb{R}$ has a basis as a $\mathbb{Q}$-vector space, so it's isomorphic to an (uncountable) direct sum $\mathbb{R} \cong \bigoplus_I \mathbb{Q}$. Its automorphism group is $\text{GL}_I(\mathbb{Q})$, which is very big, and in particular nonabelian.