How can I show that the Hilbert Symbol is bimultiplicative, when the local field is the $p$-adic numbers? Everything I can find just sort of asserts bimultiplicativity without much proof, so I'm guessing it's pretty straight forward, but I haven't done much work with the $p$-adics so I'm a little unclear.
Moreover, for what primes $p$, is it the case that there exists an element $z$ of the $p$-adics such that $(-1, z) = -1$. That is, the the Hilbert symbol acts on $-1$ and $z$ and evaluates to $-1$.
For the multiplicativity, there is a proof in Chapter III of J.-P. Serre's, A course in arithmetic.
It is also proved in that book that the Hilbert symbol is nondegenerate, meaning that if $a$ is not a square, then there is some $b$ such that $(a,b)=-1$.
When $a$ is a square, you have $(a,b)=1$, for all $b$, so the answer to your second question is there is such $z$ if and only if $-1$ is not a square in $\mathbb{Q}_p$, and this happens precisely when $p\equiv 3\bmod{4}$.