Let $f:[0,1]\to \mathbb{R}$ be a $L_1$ function (i.e., $\int_0^1 |f(x)|dx<\infty$) with $\operatorname{esssup} f=\infty$. Think of functions like $\frac1{\sqrt{x}}$ or $\frac{1}{\sqrt{x(1-x)}}$ for example (If you want to be pedantic, you can define $f(x)=0$ to be zero at the points where the functions blows up). For the first function we have singularity at $x=0$ and for the second one we have singularities at $x=0,1$.
In general I can always cook up some function $f$ that has singularity in a given set of finite points and still be in $L_1$. Something like $$f(x)=\frac{1}{\sqrt{\prod_k |x-a_k|}}$$ should work.
My question is do there exist a function $f\in L_1([0,1])$ such that this essential supremum is attained on a dense set? More precisely the converse is: For $f\in L_1([0,1])$ do there exist an open interval $I$ of $[0,1]$ such that $f_{I}$ has a finite essential supremum?
My guess is that it is not true. Given a function $f\in L_1$, I believe that the "points" where essential supremum is attained are isolated. But I can neither prove or disprove it.
I don't know if this completely answers your question but if $(r_n)$ is an ennumeration of rationals in $[0,1]$ then $f(x)=\sum_n \frac 1 {2^{n}} \frac 1 {\sqrt {|x-r_n|}}$ defines an integrable function which is (essentially) unbounded on every open interval.
Note that (by Tonelli's Theorem) $\int f(x)dx=2\sum \frac 1{2^{n}} (\sqrt {|1-r_n|} +\sqrt {r_n}) <\infty$ since $\sqrt {|1-r_n|} +\sqrt {r_n}$ is bounded. Hence $f(x)<\infty$ for almost all $x$.