How do I know if this will be rational or irrational? ($a^b$)

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Usually, when I have $a^b$ when $a$ and $b$ are both irrational, I assume that it will be irrational. But that is not always true, I assume, so when is the result irrational? How will I know?

Take something like $e^e$ or $\pi^{\pi}$ and tell me if those are irrational or rational and why.