Here the exercise:
Let $w, v \in V$. Explain why there exists a unique $x\in V$ such that $$w+3x=v$$
At this point, Axler has just outlined the definition of a vector space. In all of these, let $u,v, w\in V$.
Commutativity: $$u+v=v+u $$
Associativity: $$(u+v)+w=(w+u)+v$$
Additive Identity: There exists a $0\in V$ such that $$v+0=v$$
Additive inverse: There exists a $w$ such that $$v+w=0$$
Multiplicative Identity: $$1v=v$$
Distributive Identity: $$a(u+v)=au+av$$ $$(a+b)v=av+bv$$ For $a, b \in \mathbf{F}$, where $V$ is a vector field over $\mathbf{F}$.
I am not sure how to go about proving the existence and uniqueness of this $x$. Should I break the vector into components somehow? I don't know the dimensions of the field though.
Essentially you should "solve" for $x$ using the fact that every vector has a unique additive inverse and that the scalars form a field (say where $3$ is invertible). Then $$ w+3x=v\iff 3x=v-w\iff x=3^{-1}(v-w) $$ To be more formal you could substitute $x=3^{-1}(v-w)$ to show that it is a solution and then do a standard uniqueness proof to prove that it is the only solution.