How do you express the probability of outcomes for the next state in Markov chain (given some state)?
This is an expected value, i.e. suppose 5 states, then if one starts at state 4, then the "outcomes" from this are:
$$\sum_{k=1}^5 x_k \mathbb{P}(f_1=k|f_0=4)$$
However, I have troubles, regarding, how is this expressed using the $\mathbb{E}(...)$ syntax?
What you wrote down is how the conditional expectation is defined.
$$\mathbb{E}[X|Y=y] = \sum^n_{k=1} x_k\mathbb{P}(X = x_k | Y = y)$$