Assuming $A$ to be a square $n\times n$ matrix with $n$ distinct eigen values , then $A$ has $n$ eigen vectors $u_1,u_2,\dotsc,u_n$. Now $A^T$ has the same eigen values as $A$ and eigen vectors $v_1,v_2,\dotsc,v_n$.
Now what I observed is that for $A$, eigen value $e_1$ the eigen vector $v_1$ is perpendicular to all eigen vectors of $A^T$ which correspond to eigen value $e_i \neq e_1$ .
Can some one tell if I am correct and if yes can prove it ?
You are correct. To prove this, consider the following eigenvalue equation for $u$: $$ A u = \lambda u $$ Take the transpose of this: $$ u^T A^T = \lambda u^T $$ Now, multiply this expression on the left with $v$: $$ u^T a^T v = \lambda u^T v $$ But if $v$ is an eigenvector of $A^T$ with eigenvalue $\mu \neq \lambda$, we have $$ A^Tv = \mu v $$ so $$ u^T A^T v = \mu u^T v. $$ Therefore, $$\lambda u^T v = \mu u^T v $$ which is only true (since $\lambda \neq \mu$) if $u^T v = 0$. Since this is just the dot product, the vector $u$ must be orthogonal to the vector $v$. Thus, for an eigenvector $u_i$ with eigenvalue $\lambda_i$ of $A$, any eigenvector of $A^T$ with a different eigenvalue must be orthogonal to $u_i$.