I am not able to see why equality in the Fenchel-Young inequality characterizes subgradients.
As per Fenchel-Young inequality: \begin{equation} f(x)+f^*(u) \geq \langle x,u \rangle \end{equation} while the definition of subdifferential set says: \begin{equation} \partial f(x) = \{u: f(z) \geq f(x) + \langle u, z-x\rangle \} \end{equation} Now it holds that $u \in \partial f(x)$ at equality of Fenchel-Young inequality. Assume whatever is necessary for defining functions involved above.
Thanks.
We will show that $$f(x)+f^*(u) = \langle x,u \rangle \Longleftrightarrow u \in \partial f(x).$$
Indeed, we have \begin{align*} u \in \partial f(x) &\Longleftrightarrow f(z) \geq f(x) + \langle u, z-x\rangle \quad\forall z \\ &\Longleftrightarrow \langle u, x\rangle - f(x) \ge \langle u, z\rangle - f(z) \quad\forall z \\ &\Longleftrightarrow \langle u, x\rangle - f(x) = \sup_z\left\{ \langle u, z\rangle - f(z)\right\} \\ &\Longleftrightarrow \langle u, x\rangle - f(x) = f^*(u) \\ &\Longleftrightarrow f(x)+f^*(u) = \langle x,u \rangle, \text{QED}. \end{align*}