$$\int_0^1 \frac{\frac{\pi^2}{6}-\operatorname{Li}_2(1-x)}{1-x}\cdot \ln^2(x)\,\mathrm dx=1.03693\ldots$$
This number looks like $\zeta(5)$ value.
We expand the terms
$$\int_0^1\frac{\frac{\pi^2}{6}}{1-x}\cdot \ln^2(x) \, \mathrm dx-\int_0^1 \frac{\operatorname{Li}_2(1-x)}{1-x} \cdot \ln^2(x) \, \mathrm dx$$
$$2\zeta(2)\zeta(3)-\int_0^1 \frac{\operatorname{Li}_2(1-x)}{1-x}\cdot \ln^2(x) \, \mathrm dx$$
this last integral it is very complicate to compute...
Can any user please help to show that whether this value is equal to $\zeta(5)$ or not?
We can have a nice generalization for
$$I_n=\int_0^1\frac{\zeta(n)-\operatorname{Li}_n(1-x)}{1-x}\ln^2x\ dx=\int_0^1\frac{\zeta(n)-\operatorname{Li}_n(x)}{x}\ln^2(1-x)\ dx$$
From $$\ln^2(1-x)=2\sum_{k=1}^\infty\frac{H_{k-1}}{k}x^k$$
It follows that
$$I_n=2\sum_{k=1}^\infty\frac{H_{k-1}}{k}\int_0^1x^{k-1}(\zeta(n)-\operatorname{Li}_n(x))\ dx$$ By integration by parts we have
$$\int_0^1x^{k-1}\operatorname{Li}_n(x)\ dx=(-1)^{n-1}\frac{H_k}{k^n}-\sum_{i=1}^{n-1}(-1)^i\frac{\zeta(n-i+1)}{k^i}$$
$$\Longrightarrow I_n=2\sum_{k=1}^\infty\frac{H_{k-1}}{k}\left(\frac{\zeta(n)}{k}+(-1)^{n}\frac{H_k}{k^n}+\sum_{i=\color{red}{1}}^{n-1}(-1)^i\frac{\zeta(n-i+1)}{k^i}\right)$$
or
$$I_n=2\sum_{k=1}^\infty\frac{H_{k-1}}{k}\left(\sum_{i=\color{red}{2}}^{n-1}(-1)^i\frac{\zeta(n-i+1)}{k^i}+(-1)^{n}\frac{H_k}{k^n}\right),\quad n=2,3,...$$
Applications
$$I_2=2\sum_{k=1}^\infty\frac{H_{k-1}}{k}\left(\frac{H_k}{k^2}\right)$$
$$ I_3=2\sum_{k=1}^\infty\frac{H_{k-1}}{k}\left(\frac{\zeta(2)}{k^2}-\frac{H_k}{k^3}\right)$$
$$I_4=2\sum_{k=1}^\infty\frac{H_{k-1}}{k}\left(\frac{\zeta(3)}{k^2}-\frac{\zeta(2)}{k^3}+\frac{H_k}{k^4}\right)$$
$$I_5=2\sum_{k=1}^\infty\frac{H_{k-1}}{k}\left(\frac{\zeta(4)}{k^2}-\frac{\zeta(3)}{k^3}+\frac{\zeta(2)}{k^4}-\frac{H_k}{k^5}\right)$$