I'm searching for an easy way to give an isomorphism between two graphs since I never see it with my pair eyes and I found the following answer: This one
I tried applying it in a situation where the vertices have the same degree and things got messy and it was harder to apply it when the vertices have different degrees. This is where I tried to apply it and I got an answer but I'm sure my answer is wrong since it's based on just comparing the two matrices and saying what I thought the answer was. So my answer is:
$ k=8, a=2, b=1, e=7,\ h=6, g=4, d=3, f=9, i=10, c=5 $

Is there any way to do this better or can someone give an explanation how one can apply the matrix way to give the isomorphism in this case?


Your proposed mapping is not an isomorphism because it sends $b$ to $1$ and $c$ to $5$ and there is an edge between $b$ and $c$ but there isn't an edge between $1$ and $5$.
Usually, the best way to tell if two graphs are isomorphic is by finding structural properties of the graphs. Informally, a structural property is one that can be defined independently of the labels of the vertices. For example, if one graph contains a cycle of length $k$ and the other does not, the graphs cannot be isomorphic. If you can't find a structural property in one graph that is not present in the other, then you can try to discover an isomorphism by aligning the structural features of the two graphs.
Now let's focus on your graphs. Call the graph on the left $X$ and the one on the right $Y$. First, we observe that in both graphs, each vertex has degree exactly $3$ (i.e. the graphs are $3$-regular), but this doesn't help us distinguish the graphs.
Looking at $X$, we see that there are two cyclic subgraphs $A = \{a f, k, i, b\}$ and $B = \{d, h, c, e, g\}$ containing $5$ vertices each. Now, $A$ has the property that each vertex in $A$ is connected to exactly two other vertices in $A$ and exactly one in $B$. A similar statement holds for $B$.
Our goal is to find analogues of $A$ and $B$ in $H$. If none exist, then the graphs are not isomorphic. If they do exist, we will try to use them to find an isomorphism.
Looking at $H$ for a moment, we discover the cyclic subgraphs $A' = \{2, 3, 9, 10, 1\}$ and $B' = \{5, 7, 4, 6, 8\}$. If we assume that $A$ maps to $A'$, then suppose that our mapping $\phi$ sends $a$ to $2$. Then $\phi(d) = 5$. Continuing further, we obtain the mapping $\phi$ defined by \begin{align} a & \mapsto 2 \\ f & \mapsto 3 \\ k & \mapsto 9 \\ i & \mapsto 10 \\ b & \mapsto 1 \\ d & \mapsto 5 \\ h & \mapsto 7 \\ c & \mapsto 4 \\ e & \mapsto 6 \\ g & \mapsto 8 \end{align}
It's clear that $\phi$ is a bijection, so we can verify that $\phi$ is an isomorphism by checking that
It is slightly tedious but not difficult to verify that all three of these properties hold. If desired, this could be done by computing the adjacency matrix of the image of $X$ under $\phi$ and noting and it is equal to the adjacency matrix of $Y$.