I have already evaluated this sum:
\begin{equation*} \sum_{n=1}^{\infty}\frac{H_nH_{2n}}{n^2}=4\operatorname{Li_4}\left( \frac12\right)+\frac{13}{8}\zeta(4)+\frac72\ln2\zeta(3)-\ln^22\zeta(2)+\frac16\ln^42 \end{equation*} using the identity $\displaystyle\frac{1}{1-x^2}\ln\left(\frac{1-x}{1+x}\right)=\sum_{n=1}^{\infty}\left(H_n-2H_{2n}\right)x^{2n-1}$
but kind of lengthy. any other approaches?
using the following identity $$\frac{1}{1-z^2}\ln\left(\frac{1-z}{1+z}\right)=\sum_{n=1}^{\infty}\left(H_n-2H_{2n}\right)z^{2n-1}$$ that can be proved as follows: using Cauchy product rule, $$\frac{1}{1-z^2}\ln\left(\frac{1-z}{1+z}\right)=-2\frac{1}{1-z^2}\tanh^{-1}z=-2\left(\sum_{n=1}^\infty z^{2n-2}\right)\left(\sum_{n=1}^\infty\frac{z^{2n-1}}{2n-1}\right)\\=-2\sum_{n=1}^\infty z^{2n-1}\left(\sum_{k=1}^n\frac1{2k-1}\right)=-2\sum_{n=1}^\infty z^{2n-1}\left(H_{2n}-\frac12H_n\right)\\=\sum_{n=1}^{\infty}\left(H_n-2H_{2n}\right)z^{2n-1}$$ integrate both sides from $z=0$ to $x$, we get $$\ln^2\left(\frac{1-x}{1+x}\right)=-2\sum_{n=1}^\infty\frac{H_n-2H_{2n}}{n}x^{2n}$$ multiply both sides by $\frac{\ln(1-x)}{x}$ and integrate from $0$ to $1$, we get $$-2\sum_{n=1}^\infty\frac{H_n-2H_{2n}}{n}\int_0^1x^{2n-1}\ln(1-x)\ dx =-2\sum_{n=1}^\infty\frac{H_n-2H_{2n}}{n}\left(-\frac{H_{2n}}{2n}\right)\\ =\int_0^1\frac{\ln(1-x)}{x}\ln^2\left(\frac{1-x}{1+x}\right)\ dx$$ or \begin{align} \sum_{n=1}^\infty\frac{H_nH_{2n}}{n^2}&=8\sum_{n=1}^\infty\left(\frac{H_{2n}}{2n}\right)^2+\int_0^1\frac{\ln(1-x)}{x}\ln^2\left(\frac{1-x}{1+x}\right)\ dx\\ &=4\sum_{n=1}^\infty\frac{H_n^2}{n^2}+4\sum_{n=1}^\infty\frac{(-1)^nH_n^2}{n^2}+\int_0^1\frac{\ln(1-x)}{x}\ln^2\left(\frac{1-x}{1+x}\right)\ dx\tag{1} \end{align} lets evaluate the integral and after expanding the log, we get
$$I=\int_0^1\frac{\ln^3(1-x)}{x}\ dx-2\int_0^1\frac{\ln^2(1-x)\ln(1+x)}{x}\ dx+\int_0^1\frac{\ln(1-x)\ln^2(1+x)}{x}\ dx$$ letting $1-x=y$ for the first and second integral and using $\ln^2(1+x)=2\sum_{n=1}^\infty(-1)^n\left(\frac{H_n}{n}-\frac{1}{n^2}\right)$ for the third integral, we get \begin{align} I&=\int_0^1\frac{\ln^3x}{1-x}-2\int_0^1\frac{\ln^2x\ln(2-x)}{1-x}+2\sum_{n=1}^\infty(-1)^n\left(\frac{H_n}{n}-\frac{1}{n^2}\right)\int_0^1x^{n-1}\ln(1-x)\\ &=-6\zeta(4)-2\ln(2)\int_0^1\frac{\ln^2x}{1-x}\ dx-2\int_0^1\frac{\ln^2x\ln(1-x/2)}{1-x}\ dx\\ &\quad+2\sum_{n=1}^\infty(-1)^n\left(\frac{H_n}{n}-\frac{1}{n^2}\right)\left(-\frac{H_n}{n}\right)\\ &=-6\zeta(4)-4\ln2\zeta(3)+2\sum_{n=1}^\infty\frac{1}{n2^n}\int_0^1\frac{x^n\ln^2x}{1-x}+2\sum_{n=1}^\infty\frac{(-1)^nH_n}{n^3}-2\sum_{n=1}^\infty\frac{(-1)^nH_n^2}{n^2}\\ &=-6\zeta(4)-4\ln2\zeta(3)+2\sum_{n=1}^\infty\frac{2\zeta(3)-2H_n^{(3)}}{n2^n}+2\sum_{n=1}^\infty\frac{(-1)^nH_n}{n^3}-2\sum_{n=1}^\infty\frac{(-1)^nH_n^2}{n^2}\\ &=-6\zeta(4)-4\ln2\zeta(3)+4\ln2\zeta(3)-4\sum_{n=1}^\infty\frac{H_n^{(3)}}{n2^n}+2\sum_{n=1}^\infty\frac{(-1)^nH_n}{n^3}-2\sum_{n=1}^\infty\frac{(-1)^nH_n^2}{n^2}\quad (2) \end{align} Plugging $(2)$ in $(1)$, we get $$\boxed{\sum_{n=1}^\infty\frac{H_nH_{2n}}{n^2}=4\sum_{n=1}^\infty\frac{H_n^2}{n^2}+2\sum_{n=1}^\infty\frac{(-1)^nH_n^2}{n^2}+2\sum_{n=1}^\infty\frac{(-1)^nH_n}{n^3}-4\sum_{n=1}^\infty\frac{H_n^{(3)}}{n2^n}-6\zeta(4)}$$
I managed to prove the following sums $$\sum_{n=1}^{\infty}\frac{H_n^2}{n^2}=\frac{17}4\zeta(4)$$ $$\sum_{n=1}^{\infty}\frac{(-1)^nH_n^2}{n^2}=2\operatorname{Li}_4\left(\frac12\right)-\frac{41}{16}\zeta(4)+\frac74\ln2\zeta(3)-\frac12\ln^22\zeta(2)+\frac1{12}\ln^42$$ $$\sum_{n=1}^\infty\frac{(-1)^nH_n}{n^3}=2\operatorname{Li_4}\left(\frac12\right)-\frac{11}4\zeta(4)+\frac74\ln2\zeta(3)-\frac12\ln^22\zeta(2)+\frac{1}{12}\ln^42$$ $$\sum_{n=1}^\infty\frac{H_n^{(3)}}{n2^n}=\operatorname{Li_4}\left(\frac12\right)-\frac{5}{16}\zeta(4)+\frac78\ln2\zeta(3)-\frac14\ln^22\zeta(2)+\frac{1}{24}\ln^42$$ combining these sums, we get $$\sum_{n=1}^\infty\frac{H_nH_{2n}}{n^2}=4\operatorname{Li_4}\left(\frac12\right)+\frac{13}8\zeta(4)+\frac72\ln2\zeta(3)-\ln^22\zeta(2)+\frac{1}{6}\ln^42$$
the proof of the first, second and third sum can be found here, here and here respectively.
as for the forth sum, it can be found using the easy-to-prove generating function $\sum_{n=1}^\infty\frac{x^nH_n^{(3)}}{n}=\operatorname{Li_4}(x)-\ln(1-x)\operatorname{Li_3}(x)-\frac12\operatorname{Li_2}^2(x)$.
I hope there is a simpler solution than mine that does not reply much on the series I used.
Bonus: If we substitute these sums in (2) we get
$$\int_0^1\frac{\ln(1-x)}{x}\ln^2\left(\frac{1-x}{1+x}\right)dx=-4\operatorname{Li}_4\left(\frac12\right)-\frac{41}{8}\zeta(4)-\frac72\ln2\zeta(3)+\ln^22\zeta(2)-\frac1{6}\ln^42$$
Addendum:
Different proof for the identity above.
\begin{align} \ln^2\left(\frac{1-x}{1+x}\right)&=2\ln^2(1-x)+2\ln^2(1+x)-\ln^2(1-x^2)\tag1\\ &=4\sum_{n=1}^\infty\frac{H_{n-1}}{n}x^n+4\sum_{n=1}^\infty(-1)^n\frac{H_{n-1}}{n}x^n-2\sum_{n=1}^\infty\frac{H_{n-1}}{n}x^{2n}\tag2\\ &=4\sum_{n=1}^\infty(1+(-1)^n)\frac{H_{n-1}}{n}x^n-2\sum_{n=1}^\infty\frac{H_{n-1}}{n}x^{2n}\tag3\\ &=8\sum_{n=1}^\infty\frac{H_{2n-1}}{2n}x^{2n}-2\sum_{n=1}^\infty\frac{H_{n-1}}{n}x^{2n}\tag4\\ &=2\sum_{n=1}^\infty\frac{2H_{2n}-H_n}{n}x^{2n}\tag5 \end{align}
Explanation:
$(1)$ $(a-b)^2=2a^2+2b^2-(a+b)^2$
$(2)$ $\ln^2(1-x)=2\sum_{n=1}^\infty\frac{H_{n}}{n+1}x^{n+1}=2\sum_{n=1}^\infty\frac{H_{n-1}}{n}x^n$
$(3)$ Factoring out
$(4)$ $\sum_{n=1}^\infty (1+(-1)^n)a_{n}=2\sum_{n=1}^\infty a_{2n}$
$(5)$ $H_{n-1}=H_n-\frac1n$