I observed for the function $$ f(n)= e^n \sum_{k=0}^{n-1}\left(\dfrac{k - n}{e}\right)^k \cdot \dfrac{1}{k!} \tag 1$$
with small $n$ that
n sum
-------------
1 2.7182818
2 4.6707743
3 6.6665656
4 8.6666045
5 10.666662
6 12.666667
7 14.666667
8 16.666667
So an obvious hypothesis is $$ \lim_{n \to \infty} \bigl(f(n)-2n\bigr) = \frac 23 \tag 2$$
However, I have no idea, how to prove this but would like to understand how I can approach such a proof (I'll have then some similar ones with likely the same or related logic)
So I would like to understand ...
Q: how I could prove that assumed limit (2).
This is a pretty neat problem actually so I'm only giving you a little hint. Start by rewriting as $$\sum_{k=0}^{n-1}\frac{1}{k!}(k-n)^{k}e^{-(k-n)}=\sum_{k=0}^{n-1}\frac{1}{k!}\frac{d^{k}}{dx^{k}}e^{x(k-n)}|_{x=-1}=\sum_{k=0}^{n-1}\frac{1}{2\pi i}\int_{C}\frac{e^{z(k-n)}}{(z+1)^{k+1}}dz$$
Since $e^{z(k-n)}$ is analytic in all of $\mathbb{C}$ I applied Cauchys Integral formula and $C$ denotes an appropriate cirle that encloses the multiple singularity $z=-1$
Now feel free to expand further to a geometric sum and you shouldn't be too far from a final solution.