Consider an inner product space $V$ and $v \in V$.
It seems that the only scalar invariants a vector can have under the isometry come from $\langle v, v \rangle$. For example $\langle v, v \rangle$, $2\langle v, v \rangle^2 - 3$ or $\sin(\langle v, v \rangle)$ for real spaces etc. But how can it be proved?
I'm interested not just in a proof as is, but in insights behind it. Various proofs and/or references would be nice.
I suppose that by "the isometry" you mean the orthogonal group of all isometries. The orbits of that group are easily shown to be the sets of the $v$ with $\langle v,v\rangle=c$ for some constant $c$. Now if you have any invariant, its level sets must be unions of orbits, which for a polynomial invariant can only be a finite union for reasons of dimension. It can be seen algebraically that any polynomial function of the coordinates whose level sets are unions of sets of the form $\langle v,v\rangle=c$ is itself a polynomial in $\langle v,v\rangle$.
Added, since apparently not so obvious, an explanation why orbits are sets of the $v$ with $\langle v,v\rangle=c$ for some constant $c$. On one hand, since any isometry preserves the scalar product, it is clear that the value of $\langle v,v\rangle$ cannot vary along an orbit: $\langle v',v'\rangle=\langle g(v),g(v)\rangle=\langle v,v\rangle$ whenever there is some isometry $g$ mapping $v$ to $v'$. On the other hand if $\langle v,v\rangle=\langle v',v'\rangle=c>0$ we must find an isometry $g$ mapping $v$ to $v'$: note that $v/\sqrt c$ and $v'/\sqrt c$ are vectors of unit length, so each one can be (individually) extended to an orthonormal basis; then the linear map sending the orthonomal basis extended from $v$ to the one extended from $v'$ is such an isometry $g$.