How to see this step in deriving an equality in Fourier series?

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By convergence of Fourier series, we have $$ \frac{\pi}{4}+\sum_{n=1}^{\infty}\frac{(-1)^n-1}{\pi n^2}(-1)^n=\frac{\pi}{2} $$

Then how come we can get this from the above formula: $$ \sum_{n=1}^{\infty}\frac{1}{(2n-1)^2}=\frac{\pi^2}{8} $$?

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Note that the $n^{th}$ term of the series is zero for even $n$, so you can replace $n$ by $2n-1$ (which gives you all the odd values):

$$\sum_{n=1}^{\infty}\frac{-2}{\pi (2n-1)^2}(-1)^{(2n-1)}=\frac{\pi}{4}$$

And because $(-1)^{(2n-1)}=-1$, multiplying both sides by $\pi/2$ gives the final result.

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Note that $$ \frac{\pi}{4}+\sum_{n=1}^{\infty}\frac{(-1)^n-1}{\pi n^2}(-1)^n= \frac{\pi}{4}+\sum_{n\text{ odd}}^{\infty}\frac{2}{\pi n^2}= \frac{\pi}{2}. $$ Simplifying, $$ \sum_{n\text{ odd}}^{\infty}\frac{1}{n^2}=\frac{\pi^2}{8}\implies \sum_{k=1}^{\infty}\frac{1}{(2k-1)^2}=\frac{\pi^2}{8}. $$