If: $$3x+2y=mx+ny$$
can $m$ and $n$ take other values than $3$ and $2$ respectively, for any real values for $x$ and $y$ except $(x,y)=(0,0)$?
If no, can you please give an easy to understand proof for a $12$th grade student? Is this something related to Equating coefficients?
It depends on which values $m$ and $n$ can have. If you are searching for numbers, $m=3$ and $n=2$ are the only solutions.
More generally, you can write your equation to $mx = 3x + 2y - ny$, which is equivalent to $m=3 + \frac{2y-ny}{x} = 3 + \frac{(2-n)y}{x}$ by dividing by $x$. So you have to exclude $x=0$. Now you can choose an arbitrary $n$ and for a solution you have got to "fix" your $m$ with the formula above. Back to the beginning. If you are searching numbers, then you don't want that your solution for $m$ and $n$ depends on $x$ and $y$, so the second summand $\frac{(2-n)y}{x}$ has to be $0$, which happens, when $2-n=0$, so if $n=2$ and tehrefore $m=3$.