Let $(C, \Delta)$ be a coalgebra and $c\in C$ an element with $\Delta(c) = \Delta^{\mathrm{op}}(c)$.
For certain permutations $\sigma \in S_n$, we will have that
$$c_{(\sigma(1))} \otimes \dots \otimes c_{(\sigma(n))} = c_{(1)} \otimes \dots \otimes c_{(n)}$$
where the notation is Hopf–Sweedler notation. Is it possible to characterise/describe the permutations $\sigma \in S_n$ for which this identity holds (on the purely formal level, so you don’t need to take into account equalities that occur due to coincidences in the coalgebra itself – so say that $C$ is free as a coalgebra).
The precise set of permutations depends on $c$. For example, if $c = 0$ then every permutation does the job; but in general, not every permutation will work. So the question should probably be understood as ‘which permutations always work’.
Let us call an element $c$ of $C$ with $Δ(c) = Δ^{\mathrm{op}}(c)$ cocommutative. That $c$ is cocommutative means that $c_{(1)} ⊗ c_{(2)} = c_{(2)} ⊗ c_{(1)}$.
I assume that we are working with coalgebras over a field. By the fundamental theorem of coalgebras, every element of $C$ is contained in a finite-dimensional subcoalgebra. We may therefore assume that $C$ is finite-dimensional. The coalgebra $C$ is then isomorphic to $A^*$ for some algebra $A$, so we may assume that $C = A^*$. The comultiplication of $C$ is then the dual of the multiplication of $A$, in the sense that $$ c(xy) = c_{(1)}(x) \, c_{(2)}(y) \quad \text{for all $x, y ∈ A$.} $$ More generally, the iterated coproduct $c_{(1)} ⊗ \dotsb ⊗ c_{(n)}$ is implicitly defined via the formula $$ c(x_1 \dotsm x_n) = c_{(1)}(x_1) \,\dotsm\, c_{(n)}(x_n) \quad \text{for all $x_i ∈ A$.} $$ That $c$ is cocommutative is now equivalent to the condition $$ c(xy) = c(yx) \quad \text{for all $x, y ∈ A$.} $$ We can thus rephrase our question as follows:
This problem has a well-known special case: if $A$ is the matrix of $(n × n)$-matrices then we have $\mathrm{tr}(AB) = \mathrm{tr}(BA)$ for any two matrices $A$ and $B$. So for which permutations $σ$ do we have $\mathrm{tr}(A_1 \dotsm A_n) = \mathrm{tr}(A_{σ(1)} \dotsm A_{σ(n)})$? It is a common false belief that this holds for all permutations (see https://mathoverflow.net/a/23481/200357), but the case of $n = 2$ only generalizes to cyclic permutations, i.e., $$ \mathrm{tr}(A_1 \dotsm A_n) = \mathrm{tr}(A_2 \dotsm A_n A_1) = \mathrm{tr}(A_3 \dotsm A_n A_1 A_2) = \dotsb = \mathrm{tr}(A_n A_1 \dotsm A_{n-1}) \,. $$
The same principle also works for the general question:
The cyclic permutations are in fact the only permutations that always work. To prove this, it suffices to consider the above special case of matrices and the trace.
To prove this claim we consider the standard basis matrices $E_{ij}$ (with $E_{ij} E_{kl} = δ_{jk} E_{il}$) and set $$ A_1 = E_{12} \,, \quad A_2 = E_{23} \,, \quad \dotsc \,, \quad A_{n-1} = E_{n-1, n} \,, \quad A_n = E_{n 1} \,. $$ We have $$ \mathrm{tr}(A_1 \dotsm A_n) = \mathrm{tr}(E_{11}) = 1 \,. $$ But for every non-cyclic permutation $σ$ we have $$ A_{σ(1)} \dotsm A_{σ(n)} = 0 \,, $$ because at some point we have $A_{σ(i)} A_{σ(i+1)} = 0$ since the indices don’t match up.