My intuition is that if something is larger than $\mathbb{N}$ then it follows that it is larger than $\mathbb{Q}$ as there is a bijection from $\mathbb{N}$ to $\mathbb{Q}$. So if a set is larger than $\mathbb{Q}$, which is the boundary before going into $\mathbb{R}$, then it must be uncountably infinite.
But I am not sure if this is valid.
Yes, if $|A| > |\mathbb N|$, then $A$ is uncountable (and infinite). [This is not the Cointinuum Hypothesis. ]
On the other hand, you wrote $|A| > \mathbb N$. What does that mean? Do you mean $|A| > k$ for all $k \in \mathbb N$? In that case, it does not follow that $A$ is uncountable. For example $A = \mathbb N$ satisfies this.
Another warning. $|A| > |\mathbb N|$ means: there is an injective map $\mathbb N \to A$, but there is no injective map $A \to \mathbb N$. It is not enough to show there is a map $\mathbb N \to A$ that is injective but not surjective. That would only show $|A| \ge |\mathbb N|$