The two compatibility conditions for an ordered field F are that:
$ \begin{align} x, y, z\in F, & y < z \implies x + y < x + z\\ x, y\in F, & 0 < x, y \implies 0 < xy \end{align} $
Suppose we create an order on the field of real numbers that is somewhat compatible, in the sense that the first condition is satisfied.
Then must this order be our usual order (or the opposite)? Or could some really bizarre order work?
It is easy to show that the first condition implies that $<$ on $\Bbb Q$ is either the usual order or the reverse of the usual order.
Consider $\Bbb R$ to be a vector space over the ordered field $\Bbb Q.$ Let $B$ be a vector-space (Hamel) basis for $\Bbb R$ over $\Bbb Q$. For each $x\in \Bbb R$ there exists a unique $f_x:B\to \Bbb Q $ such that (i) $\{b\in B: f_x(b)\ne 0\}$ is finite, and (ii) $x=\sum_{b\in B}bf_x(b).$
Let $<$ be an order on $\Bbb Q$ that obeys the first condition. Let $<_W$ be any well-ordering of $B$. Now for $x,y\in \Bbb R$ with $x\ne y$ let $b_0$ be the $<_W$-least $b\in B$ such that $f_x(b)\ne f_y(b).$ And define $x<'y \iff f_x(b_0)<f_y(b_0).$ Then $<'$ obeys the first condition. Since there are many different well-orders on the set $B$ there are many different linear orders on $\Bbb R$ that obey the first condition.
BTW. Some proper sub-fields of $\Bbb R$ can be ordered fields with orders different from the usual order, but obeying the first and second conditions. E.g. $\{a+b\sqrt 2\;: a,b\in \Bbb Q\}$ with $1>0>\sqrt 2\;.$