I'm reading about Hurewicz theorem and just wondered if it works this way. Stupid question, but I was thinking whether n-connectedness in the theorem means just that $\pi_i(X)=0$ for all $i=0,\dots,n$ or that in addition $\pi_{n+1}(X)$ must be non-trivial.
Thank you.
I don't think it's a stupid question. It's just a matter of getting the definitions straight. I looked it up and $n$-connected means the first $n$ homotopy groups are trivial. There is nothing about $\pi_{n+1}$.
So for example an $n$-sphere is $n-1$ connected. Of course, we know the unstable homotopy groups ($\pi_{n+k}\,,k\lt n+2$) can be nontrivial. Consider for instance the Hopf fibration. But not that they always are.
I guess to zero in on your question better, what about $\Bbb R^n$. All its homotopy groups are trivial, but it's pretty clear it's $n$-connected.
For your title question, $1$-connected implies $H_*:\pi_2 X\to H_2 X$ is an isomorphism. I see this got answered in the comments.