If $\tan 2\alpha\cdot\tan \alpha = 1$, then what is $\alpha$?
I tried two methods but got two different answers.
Method 1:
$$\begin{align} \tan 2\alpha\cdot\tan \alpha = 1 &\implies \frac{2\tan \alpha}{1 - \tan ^2 \alpha}\;\tan \alpha = 1 \tag{1a}\\[6pt] &\implies 2\tan ^2\alpha = 1 - \tan ^2\alpha \tag{1b}\\[6pt] &\implies \tan ^2 \alpha = \frac{1}{3} \tag{1c}\\[6pt] &\implies \tan \alpha = \pm\frac{1}{\sqrt 3} \tag{1d}\\[6pt] &\implies \tan \alpha = \tan\left(\pm\frac{\pi}{6}\right) \tag{1e}\\[6pt] &\implies \alpha = n\pi \pm \frac{\pi}{6} \;\text{where}\; n \in \mathbb{Z} \tag{1f} \end{align}$$
Method 2: $$\begin{align} \tan 2\alpha \cdot \tan \alpha = 1 &\implies \tan 2\alpha = \frac{1}{\tan \alpha} \tag{2a}\\[6pt] &\implies \tan 2\alpha = \cot \alpha \tag{2b}\\[6pt] &\implies \tan 2\alpha = \tan\left(\frac{\pi}{2} - \alpha\right) \tag{2c}\\[6pt] &\implies 2\alpha = n\pi + \frac{\pi}{2} - \alpha \text{?} \tag{2d}\\[6pt] &\implies \alpha = \frac{1}{3}\left(n\pi + \frac{\pi}{2}\right)\;\text{where}\; n \in \mathbb{Z} \tag{2e} \end{align}$$
Which one is correct? Is there any mistake in the above solutions?
Note carefully for future reference that in solving equations you need to use $\Leftrightarrow$ not $\Rightarrow$, or to do something equivalent.
Both your answers are correct as far as they go, but incomplete.
In your first method, for $\alpha=n\pi+\frac\pi6$ we check that $$\tan2\alpha\tan\alpha=\sqrt3\frac1{\sqrt3}=1\ ,$$ so this is a correct solution, while for $\alpha=n\pi-\frac\pi6$ we have $$\tan2\alpha\tan\alpha=(-\sqrt3)(-\frac1{\sqrt3})=1\ ,$$ so this is also a correct solution.
For your second solution there are three cases: $n=3k$ or $n=3k+1$ or $n=3k+2$. The first gives $$\tan2\alpha\tan\alpha=\sqrt3\frac1{\sqrt3}=1\ ,$$ so this is a correct solution. The second gives $\alpha=k\pi+\frac\pi2$, so $\tan\alpha$ is undefined and this must be ruled out. The third gives $$\tan2\alpha\tan\alpha=\sqrt3\frac1{\sqrt3}=1\ ,$$ so this is also a correct solution. Therefore your second method should give an answer $$\alpha=\tfrac13(n\pi+\tfrac\pi2)\ ,\quad\hbox{where $n=3k$ or $n=3k+2$}.$$ The actual numbers obtained in this solution are then the same as in your first method.
Always check your answers if you start with an equation and derive (potential) solutions.