In my understanding, predicates are synonyms of relations: mappings of an ordered set (a,b) to the set of values "True" and "False"
Well, propositional calculus comes before predicate calculus, and we have relations in propositional calculus.
I mean, I believe that all connectives are relation symbols: sentences involving connectives must be mapped either to "True" or to "False", in other words, they have truth values.
This leads to me to the question: why is Predicate Calculus called Predicate Calculus if there are predicates in Propositional Logic?
The name predicate calculus has an historical heritage ...
Today we prefer to call it first-order logic.
For the "founding fathers" : Frege, Russell, the distinction between propositional and predicate calculi were not relevant; see Principia Mathematica and The Notation in Principia Mathematica.
In the first modern mathematical logic textbook :
we can find the distinction between sentential calculus and predicate calculus; see page 44 :
In the early authoritative textbook :
we have : propositional calculus and functional calculus of first order.
According to Church's Historical note [page 288] :