If $\vec{\nabla} \times \langle P,Q,R\rangle=\vec{0}$ iff $Pdx+Qdy+Rdz$ is an exact differential form.
My attempt:-
If $Pdx+Qdy+Rdz$ is an exact differential form. Then there exists $U(x,y,z): dU=Pdx+Qdy+Rdz$. From the mixed partial theorem, It is easy to prove that $curl \langle P,Q, R\rangle=\vec{0}$.
If $\vec{\nabla} \times \langle P,Q,R \rangle=\vec{0}$
$\implies R_y=Q_z,R_x=P_z $ and $Q_x=P_y$. How do I prove the existence of scalar function $U$:$dU=Pdx+Qdy+Rdz$?
This is quite standard. However, you need an additional assumption to prove your result. The easiest is to assume that the domain on which $dU$ is defined is a star domain.
You can then find $U$ by simply integrating $dU$ from $\vec{r}_0= (x_0,y_0,z_0)$ to $\vec{r}=(x,y,z)$ along the path $$\vec{\gamma(}t) = t\vec{r}_0+ (1-t)\vec{r},\qquad t\in[0,1].$$ In particular, we set $$U(\vec{r}) = \int_{\gamma}(Pdx+Qdy+Rdz)\,. \tag{1} $$
Now, what is left to show is that $dU$ is indeed $(P,Q,R)$. The relevant property thereby is that in (1) the value of $U$ is independent of he path choses (and only depends on the endpoints). This fact is due to Stokes theorem and the vanishing of the curl. The result then follows from the fundamental theorem of calculus.