The definition of a group monomorphism is as follows:
Let $G$ and $H$ be groups and suppose $\phi:G\to H$ is a group homomorphism. Then $\phi$ is a group monomorphism if and only if $\phi$ is an injection.
There are so many morphisms to keep track of in group theory that I some times lose track of what I am trying to prove. If we go by this definition, it suffices to show that $\phi$ is a well-defined homomorphism between $G$ and $H$ and then to show that $\phi$ is injective.
So here is an example from Algebra (Hungerford) page 64:
Let $\left\{G_i | i\in I\right\}$ be a family of groups and $J\subset I$. The map $\alpha: \prod_{j\in J} G_{j} \to \prod_{i\in I} G_{i}$ given by $\left\{a_{i}\right\}\mapsto \left\{b_{i}\right\}$, where $b_{j} = a_{j}$ for $j\in J$ and $b_{i}=e_{i}$ for $i \notin J$, is a monomorphism of groups and $\prod_{i\in I} G_{i} /\alpha(\prod_{j\in J} G_{j})$ is isomorphic to $\prod_{i\in I-J} G_{i}$.
Based on my understanding, the first part of this is to show that $\alpha$ is well-defined and then to show it is injective. Am I understanding this correctly?
The second part showing $\prod_{i\in I} G_{i} /\alpha(\prod_{j\in J} G_{j})$ is isomorphic to $\prod_{i\in I-J} G_{i}$ is not really a concern at the moment.
Yes. You need to show that $\alpha$ is a well-defined group homomorphism then show that it's injective.