In $S_{4}$, find a Sylow 2-subgroup and a Sylow 3-subgroup.
With everyone's comments and inputs, I have outlined the following answer:
We have $|S_{4}|= 24 = 2^{3}3$. If $P$ is a Sylow $2$-subgroup then $|P| = 2^3$, and if $K$ is a Sylow $3$-subgroup then $|K|=3$. So we need to find subgroups of $S_4$ of order $8$ and order $3$. For the subgroup of order $3$, since it is of prime order, it is cyclic, thus we need to find an element of $S_4$ of order $3$. So any $3$-cycle of $S_4$ will suffice. As a concrete example, we will call $K = \langle(1\ 2\ 3)\rangle$.
Now we must find $P$. Since $|P| = 8$, every element in $P$ must have order $1$, $2$ or $4$. We can choose a dihedral subgroup $D_4$ to be $P$. For example
$$P= \lbrace e, (1234), (13)(24), (1432),(24) ,(14)(23), (13), (12)(34)\rbrace.$$
You seem to have misunderstood some part of the Sylow theorems: It is not true that $n_2$ and $n_3$ divide $3$. The Sylow theorems state that $n_2\mid3$ and $n_2\equiv1\pmod2$, and that $n_3\mid2^3$ and $n_3\equiv1\pmod3$.
The problem is to find (and describe) two Sylow-subgroups of $S_4$. As you have noted, because $|S_4|=2^3\times3$ every Sylow-$3$ subgroup is of order $3$. It should not be difficult to find and describe such a subgroup.
Every Sylow-$2$ subgroup is of order $2^3=8$. So all its elements have order $1$, $2$, $4$ or $8$. There are no elements of order $8$ in $S_4$, so we should look at elements of orders $2$ and $4$. There aren't that many of those, and trying a few combinations should give you a subgroup of order $8$ rather quickly.