How do I prove the claim of the title?
My definition of Lie Group homomorphism is a smooth group homomorphism. I have to show that $Df(e)(v)=0$ will imply $v=0$. Viewing this as a derivation, this means $Df(e)(v)(g)=0$ for all smooth functions $g$ on $H$.
Here $f$ is the Lie group homomorphism from $G$ to $H$.
Suppose that $Df_e(v)=0$. Then $(\forall t\in\mathbb R):Df_e(tv)=tDf_e(v)=0$. And therefore$$(\forall t\in\mathbb R):\exp\bigl(Df_e(tv)\bigr)=e.$$But then$$(\forall t\in\mathbb R):f(e^{tv})=e$$and therefore $f$ is not injective.