I was wondering what might be a good way to learn graph theory from scratch. I have a basic background in math (calculus, diffeq, linear), and thought that I might be able to pick up Diestel's book as it suggested it as a good "first course" in graph theory, but knew it was over my head on literally the first sentence:
Is there a more friendly introduction to graph theory that assumes no previous knowledge on these notational elements? What might be a good place to start?

With no background in combinatorics, I recommend starting with Discrete Mathematics: Elementary and Beyond by Lovász, Pelikán, and Vesztergombi. This covers basic counting techniques and elementary set theory, but out of 15 chapters total, chapters 7-10 and 12-13 are on topics in graph theory.
After looking at a couple of other books, here are the things that (in my mind) make this one stand out:
I think that this makes the book easier to read, and modeling things by graphs is a genuinely useful skill that deserves to be taught by lots and lots of examples. The drawback is that there will be a bit more of a learning curve, at first, if you go on to an advanced source like Diestel which is written very formally and concisely.