Given finite-dimensional vector spaces $V,W$, there is an isomorphism $\text{Hom}(V,W) \rightarrow V^* \otimes W$. In particular, any linear map $\phi : V \rightarrow W$ has a tensor expansion $\sum v^*_i \otimes w_i$ where $v^*_i \in V^*, w_i \in W$.
For example, if one chooses dual bases $\{x_i\}, \{e_i\}$ of $V^*$ and $V$, then $\sum x_i \otimes e_i \in V^* \otimes V$ is a tensor expansion for the identity map on $V$.
What's the best way to intuitively understand tensor expansions of linear maps?
Ok, let's try to incorporate your question in a more gneral setting: at least one of the vector spaces in the following is finite-dimensional.
Let $f\colon U\to U'$ and $g\colon V\to V'$ be linear maps. We easily define the "tensor product" of $f$ and $g$ to be the map $f\otimes g$ such that $$ (f\otimes g)(u\otimes v)=f(u)\otimes g(v) $$ for all $u\in U$ and $v\in V$. So, we obtain a linear map $$ \lambda\colon\hom(U,U')\otimes \hom(V,V')\cong \hom(V\otimes U, V'\otimes U'),$$ which is easily checked to be an isomorphism, provided at least one of the pairs $(U,U')$, $(V,V')$, $(U,V)$ consists of finite-dimensional vector spaces.
With an intelligent choice of the spaces, the isomorphism $\lambda$ allows us to prove every sort of useful identity relating tensor product of spaces and their duals: Try putting $U'=V'=\mathbb{K}$ (the underlying field), you'll obtain $(V\otimes U)^\star\cong U^\star\otimes V^\star $ (don't worry for the twist). Try putting $U=V'=\mathbb{K}$, you'll obtain... $\lambda_{UV}\colon V\otimes U^\star\cong \hom(U,V)$.
Now, let $f\colon U\to V$ be a linear map. Using bases for $U$ and $V$, we have $$f(u_j) = \sum_i f_i^j v_i$$ for a family $(f_i^j)$ of scalars. Try proving that $$ f = \lambda_{UV}\Big(\sum_{ij} f_i^j v_i\otimes u^j\Big). $$