Why is it different to make one choice or many choices than to make infinite choices from a theoretical point of view in which indeed you are not going to do any?
How could that be different from making infinite additions for example $\sum_{i=0}^{+\infty}A_n$.
Thanks a lot.
Making one choice is simple, if a set $A$ is not empty, then $\exists a(a\in A)$, and therefore we can pick such $a$. This is called existential instantiation. But this choice is completely arbitrary. This is important because in mathematics we are always within the context of writing a proof (even if we only play around, we essentially prepare ourselves for such proof).
However making infinitely many arbitrary choices is something we cannot prove to be possible1. The axiom of choice asserts that we can, in fact, many infinitely many choices at once - as long as we could make each one (i.e. the sets were not empty).
Remember that arbitrary sets have absolutely no structure. We only have $\in$ in our language, and we have sets and their elements. Sometimes we are lucky and the elements of the set are nice enough to allow for a definable way of choosing from them. For example if the empty set is a member or something.
But this need not be the case. The axiom of choice allows us to uniformly endow all the sets with a particular structure from which we can define a selection.
In comparison, addition of infinitely many real numbers happens within a complete ordered field, where we have some structure, and we use it to establish a criterion when the sum is finite, and if so what is its value.
Footnotes:
I am being deliberately imprecise here. The axiom of choice is more than a generalization of existential instantiation for the infinite case. But the intuition which should guide you, in my opinion, is that.
To give a small taste on why things may break down, if we are working within a universe which has non-standard integers then there would be a product which is finite (from the point of view of that model) and therefore is not empty, but since its index set is a non-standard integer we cannot possible write down a formula which instantiate an element from each set.
But all this require first to understand what does internal and external mean in these contexts, and to understand what are non-standard integers and non-standard models better. So it's all pretty far along the road. It is my firm belief that one should start with the idea that the axiom of choice is indeed some sort of a generalization of existential instantiation, and then learn why it is not.