I'm trying to get deeper intuition into the exterior algebra construction on a finite dimensional $\mathbb{R}$-vector space.
Our accustomed notion of volume given by measure is neither multi-linear nor anti-symmetric, so I don't buy construction of a 'volume function' as an a priori motivation for an exterior algebra.
It's great that $v_1 \wedge \cdots \wedge v_n = \alpha \ e_1 \wedge \cdots \wedge e_n$ computes the (signed) volume $\alpha$ of the parallelotope spanned by these vectors.
But this fact seems rather arbitrary and a priori unexpected.
It would be nice to have a narrative as to why constructing an exterior algebra on a vector space is just the natural thing to do. For instance, generalizing from metric spaces to topological spaces is very natural once we realize that metrics just generate open sets, and that continuity of functions can be characterized by their behavior on open sets alone.
Is there any reason why one would intuitively anticipate beforehand that constructing an alternating algebra on a vector space would give a device to compute volumes, detect linear dependence etc.?
Or should the recognition of these facts just be considered a random encounter in the process of experimentation with mathematical constructs?
I had some of the same thoughts you're describing in this post about the whole philosophy behind alternating forms and exterior algebra. The thing that started making things click for me was reading Terry Tao's introduction to differential forms.
Basically at one point he describes how in the univariate calculus we get in school, three notions of integration are actually slurred together. For me, properties of one notion were actually interfering with my understanding of another.
While classical measure theory has us focus on nonnegative set functions to measure sets, differential geometry (or maybe I should say algebraic topology) chooses objects that retain information about orientation of $n$-dimensional volumes.
This is going to be badly explained, and experts are probably going to have a lot to say by way of correction, but here goes.
One intuition I have is that orientation and alternativity give you what you need to stack cells against each other and keep track of their surface area. For instance, you can think of the faces of two cubes joined on one side as having a "surface" consisting of a combination of oriented squares. Individually the cubes have six oriented squares on their surface, but together there are $10$ squares tiling the surface. The square shared on their common side has opposite orientations on each cube, so they cancel out when they make contact. These collections of squares are examples of chains (in this sense).