Zero-set means a set of the form:
$Z(f) = \{ x \in X | f(x) = 0 \}\quad\text{for some } f \in C(X)$
$C(X)$ is the ring of continuous function on $X$.
I know that every zero-set is $G_\delta $, i.e, a countably intersection of open sets.
Is every $G_\delta $, zero-set? if not, can you give me an simple example.
Trivially not, in general: there is no continuous function on $\mathbb{R}$ whose zero set is $(0,1)$, since if $f$ were such a function, then it would satisfy $$f(1) = \lim_{x\to1}f(x) = \lim_{x\to1^-}0 = 0,$$ so $1 \in Z(f)$, so $Z(f) \neq (0,1)$, but as an open set, $(0,1)$ is clearly $G_\delta$: it is the intersection of countably many copies of itself.