Obviously:
$$\frac{1}{10}+\frac{1}{100}+\frac{1}{1000}+\cdots=0.1111\dots=\frac{1}{9}$$
is a rational number.
Now, if we make terms with demoninators in the form:
$$q_n=\sum_{k=0}^{n} 10^k$$
Then the sum will be:
$$\sum_{n=1}^{\infty}\frac{1}{q_n}=\frac{1}{11}+\frac{1}{111}+\frac{1}{1111}+\cdots=0.1009181908362007\dots$$
The decimal expansion of this number appears to be non-periodic.
How can we prove/disprove that this number is irrational?
Edit
This number is at OEIS: http://oeis.org/A065444
If we define the "Lambert series" $$ f(x) = \sum_{n=1}^\infty \frac{x^n}{1-x^n} = \sum_{n=1}^\infty \frac{1}{(1/x)^n-1}, $$ then since $q_n = (10^{n+1}-1)/9$, your number is $$ \sum_{n=1}^\infty \frac1{q_n} = 9f(\tfrac1{10})-1. $$ Chowla proved in 1947 that $f(\frac1{10})$ is irrational, and hence so is your number. You can find a proof in this 1948 paper of Erdös.
(Interesting side note: we also have $$ f(x) = \sum_{m=1}^\infty \tau(m)x^m, $$ where $\tau(m)$ is the number of positive divisors of $m$.)