I know, it may sound as nothing but a provocative question, and probably it is. However I've been thinking about it for a while, despite being aware that the question itself may not have much sense.
Consider the field $\mathbb{R}$. Each element can be defined univocally. First $0$ and $1$, then the integers, so the rationals and then all the others (for instance as equivalence classes of Cauchy sequences on $\mathbb{Q}$).
Now we can define the complex field $\mathbb{C}$ as $$\mathbb{C} = \mathbb{R}[X]/(X^2+1)$$ where $\mathbb{R}[X]$ is the ring of polynomials with real coefficient. However here it becomes impossible to univocally define a root of the polynomial $X^2+1$ since it has two roots (which we will eventually call $\pm i$) and they are totally indistinguishable. I know that in practice it's not a problem, we just decide to call one of the two roots $i$ and the other $-i$. But what's going on exactly? Is it some kind of "axiom" the fact that we are allowed to choose one out of a set of two identical elements?
No, it is not well-defined. The reason is that complex conjugation is a field automorphism of $\mathbb{C}$. This means that the act of complex conjugation respects multiplication and addition. So any statement using field operations and the real numbers that holds for $\mathrm{i}$ also holds for $-\mathrm{i}$.
If you want to make it well defined, you need something that breaks complex conjugation, and thus separates $\mathrm{i}$ from $-\mathrm{i}$. Putting an orientation on the complex plane will do that for you, but that is putting the cart before the horse somewhat, because it presupposes that you have chosen $\mathrm{i}$.
Edit: there appears to be some issue around the definition of 'well-defined'. I am taking as my definition that there is a description of it that uniquely determines it using properties of the field. Any definition of $\mathrm{i}$ that you can come up with will equally apply to $-\mathrm{i}$, and in that sense it is not well-defined.