Let $f, g\in L^{2},$ by Plancherel's theorem, we have
$$\langle f, g \rangle= \langle \hat{f}, \hat{g} \rangle.$$
My Question is: Is it true that: $$\langle f, g \rangle= \langle \hat{f}, \hat{g} \rangle$$
for $f\in \mathcal{S'}(\mathbb R^d)$ (tempered distribution) and $g\in \mathcal{S}(\mathbb R^d)$(Schwartz space)? If yes, how to justify.
One has to be careful with complex conjugation here. The claimed identity is $$ \int f \bar g = \int \hat f \bar {\hat g} \tag1$$ Conjugating the (unitary) Fourier transform gives the inverse Fourier transform of conjugation. So,
$$ \int \hat f\bar {\hat g} = \int \hat f \check {\bar g} \tag2$$ The right hand side is the value of distribution $\hat f$ on test function $\check {\bar g} $. By the definition of $\hat f$, this is computed by passing the hat to the test function, which cancels out the inverse hat: $$ \int \hat f \check {\bar g} = \int f \bar g \tag3$$