I was trying to show that $\sin(x)$ is non-zero for integers $x$ other than zero and I thought that this result might emerge as a corollary if I managed to show that the result in question is true.
I think it's possible to demonstrate this by looking at the power series expansion of $\sin(x)$ and assuming that we don't know anything about the existence of $\pi$.
All of the answers below insist that the proposition '$\exists p,q \in \mathbb{Z}, \sin(p)=\sin(q)$' -where $\sin(x)$ is the power series representation-is undecidable without using the properties of $\pi$. If so this is a truly wonderful conjecture and I would like to be provided with a proof. Until then, I insist that methods for analyzing infinite series from analysis should suffice to show that the proposition is false.
Note: In a previous version of this post the question said "bijective" instead of "injective". Some of the answers below have answered the first version of this post.
Suppose that we define the function $\def\RR{\mathbb R}f:\mathbb R\to\mathbb R$ putting $$f(x)=\sum_{n=0}^{\infty} \frac{(-1)^nx^{2n+1}}{(2n+1)!}$$ for each $x\in\mathbb R$, after checking that the power series converges for all real $x$. It is easy to compute derivatives of functions defined by power series, and therefore it is trivial to show that $$f''(x)=-f(x) \tag{1}$$ for all $x\in\RR$. We have $$\frac{d}{dx}(f(x)^2+f'(x)^2) = 2f'(x)(f''(x)+f(x))=0$$ for all $x\in\RR$, so $f(x)^2+f'(x)^2$ is a constant function. Evaluating it at $0$, we see at once that $$f(x)^2+f'(x)^2=1 \tag{2}$$ for all $x\in\RR$.
Equation (1) tells us that $f$ and $f'$ are solutions to the linear differentia equation $$u''+u=0.$$ Their Wronskian is $$\begin{vmatrix}f&f'\\f'&f''\end{vmatrix}=-(f^2+f'^2)$$ is nowhere zero, according to (2), so that $f$ and $f'$ aare linearly independent. Since the differential equation is of order $2$, we see that $\{f,f'\}$ is a basis of its solutions.
Now fix $y\in\RR$ and consider the functions $g(x)=f(x+y)$ and $h(x)=f'(x)f(y)-f(x)f'(y)$. Using (1) we find at once that they are both solutions to out differential equation, and clearly $g(0)=h(0)$ and $g'(0)=h'(0)$, so the uniqueness theoreem of solutions to initial value problems tells us that $g$ and $h$ are the same function, that is, that $$f(x+y)=f'(x)f(y)-f(x)f'(y) \tag{3}$$ for all $x$ and, s ince $y$ was arbitrary, for all $y$. Compuing the derivative with respect to $y$ in this equation an using (1), we find that also $$f'(x+y)=f'(x)f'(y)+f'(x)f'(y) \tag{4}$$ for all $x$ and all $y$.
I claim that
Once we have checked this, we may compute, using (3) and (4) that \begin{align} f(x+2p) &= f'(x+p)f(p)-f(x+p)\underbrace{f'(p)}_{=0}\\ &=(f'(x)\underbrace{f'(p)}_{=0}+f(x)f(p))f(p) \\ &= f(x)f(p)^2. \end{align} In view of (2) and out choice of $p$, we have $f(p)\in\{\pm1\}$, and therefore $f(p)^2=1$ and we have proved that $$f(x+2p)=f(x)$$ for all $x\in\RR$, that is, that $f$ is a periodic function and that $2p$ is one of its periods.
Let us prove our claim. To do so, suppose it is false, so that $f'(x)\neq0$ for all $x\in(0,+\infty)$. Since $f'(0)=1$ and $f'$ is continuous on $[0,+\infty)$, we see that in fact $f'(x)>0$ for all $x\in[0,\infty)$ and, therefore, that $f$ is strictly increasing on $[0,\infty)$. In view of (2), we have $f(x)\leq1$ for all $x\in[0,infty)$ so we know that the limit $\alpha=\lim_{x\to\infty}f(x)$ exists and is an element of $[0,1]$. As $f'(x)^2=1-f(x)^2$, $f'(x)^2$ converges to $1-\alpha^2$ as $x\to\infty$ and, since $f'(x)$ is positive on $[0,+\infty)$, we see that $\lim_{x\to\infty}f'(x)$ is the positive square root $\beta=\sqrt{1-\alpha^2}$.
Pick any $y\in\RR$. For all $x\in\RR$ we have that $$f(x+y)=f'(x)f(y)-f(x)f'(y).$$ Taking limits on both sides of this equality as $x\to\infty$ we find that $$\alpha=\beta f(y)-\alpha f'(y).$$ This holds for all $y$, so we may differentiate it with resprect to $y$, and we see that $$0=\beta f'(y)-\alpha f''(y)=\beta f'(y)+\alpha f(y).$$ This is absurd, as $f$ and $f'$ are linearly independent functions.
Let now $P$ be the set of positive real numbers $p$ such that $2p$ is a period of $f$. We have shown that $P$ is not empty. Let $\pi=\inf P$. If $\pi=0$, there exists a sequence $(p_i)_{i\geq1}$ of elements of $P$ converging to $0$, and then $$1=f'(0)=\lim_{i\to\infty}\frac{f(2p_i)-f(0)}{2p_i}=0.$$ Therefore $\pi$ is a positive number. Now we may use, for example, the argument of Bourbaki to show that $\pi$ is irrational. That works because our arguments above easily show that $f(x)>0$ if $x\in(0,\pi)$, which is one of the things needed, and we can do the required integration by parts using (1).
All this shows in fact that
What you want, follows form this.