maybe that's an idiot question. Given a finite field $k$ and some irreducible polynomial $f(x) \in k[x]$, then $k_f \cong k[x]/(f(x))$? I know that it's true if $k$ is the prime field and I think that the statement is not true for general finite fields, however I could not find any counter example.
Thanks in advance.
Yes, this is true. Basically it is one of the reformulations of the fact that all extensions of fields $\ell/k$ with both $\ell$ and $k$ finite are Galois.
Another way of making this very concrete is that we know the Galois group to be generated by the Frobenius automorphism $F(x)=x^q$, $q=|k|$. So if $\alpha$ is one of the roots of $f(x)$ in $k_f$, then $\alpha^q$, $\alpha^{q^2}$, $\alpha^{q^3}$, $\ldots$ are the others.
It is easy to see that if $m$ is the smallest positive integer with the property that $F^m(\alpha)=\alpha$, then the polynomial $$ (x-\alpha)(x-F(\alpha))\cdots(x-F^{m-1}(\alpha)) $$ is invariant under $F$. Hence it belongs to $k[x]$, hence it must be equal to $f(x)$.