I understand that graphs do not have any notion of "facing", that is, a sense of relative or cardinal directions. Using a conventional graph, it's not possible to say "go left at vertex A," as far as I understand it.
However, I'm wondering if there is any such structure — that is, one which can represent vertices and edges, as well as a sense of what one might refer to as direction or orientation.
Suppose I'm standing on vertex A. Vertex A is connected to vertex Z, with several vertices in-between, some of which have edges which lead elsewhere. Assume I'm forbidden from naming the intermediate vertices/edges. How can I describe the path from A to Z?
One possibility is to use a rotation system. Since that link is a little technical, here's a slightly more basic way to think of a rotation system that may be more suitable to your purposes. A rotation system is a function $\Phi$ that assigns to each vertex $v \in V(G)$ an ordered sequence consisting of all neighbors of $v$ in $G$. A rotation system is usually thought of as representing an embedding of a graph in a particular surface, so that if $\Phi(v) = (v_1, v_2, \dots, v_i)$, then the edges $(v,v_1),(v,v_2),\dots, (v, v_i)$ are embedded in that order clockwise around $v$ in the surface.
There are then a couple ways you could define paths using the rotation system for $G$:
A path can be described by a sequence consisting of two vertices and integers. For example, $(u,v,1,4)$ could describe the path in $G$ beginning with the edge $(u,v)$, followed by the edge $(v,w)$ that is $1$ edge clockwise of $(u,v)$ at $v$, and finally the edge that is $4$ edges clockwise of $(v,w)$ at $w$.
Or, you could think of the first element $u$ of $\Phi(v)$ as a special vertex, so that you could think of $(u,v)$ as being oriented "north", say. Then a path could be described as a vertex together with a sequence of integers. For example, $(u,1,4,2)$ could represent the path beginning at $u$, going to the first element $v$ in the sequence $\Phi(u)$, then the fourth element $w$ in $\Phi(v)$, and finally the second element of $\Phi(w)$.