Is there any proposition $\mathcal{P}(n)$ such that $\mathcal{P}(n)$ is true $\forall n \in \mathbb{N}$ but cannot be deduced using induction (regardless of its being true? i.e. $\mathcal{P}(k)$ being true does not necessarily implies that $\mathcal{P}(k+1)$ is also true.
Are there formal problems that cannot be proven using mathematical induction but require the use of direct proof?
Goodstein's theorem is a well-known and "purely number-theoretic" theorem about natural numbers that can be expressed by means of a first order statement in the language of arithmetic but cannot be proved in first-order Peano Arithmetic, in particular cannot be proved by induction on $\mathbb{N}$. This thorem states that every Goodstein sequence eventually terminates at 0. The definition of Goodstein sequence is quite technical, see the Wikipedia page.