If $f$ is a positive function, the intuitive interpretation of the Riemann integral
$\int_a^b f(x) dx$
is the area under the curve $f$ between $a$ and $b$.
Suppose $f$ and $g$ are smooth positive functions. Is it correct to interpret the Riemann-Stieltjes integral
$\int_a^b f(x) d g(x)$ as the volume under a "ribbon", where the height of the ribbon at a point $u$ between $a$ and $b$ is determined by $f$ and the thickness is determined by $g'$?
You are effectively replacing $\int_a^b f(x) dg(x)$ with $\int_a^b f(x) g'(x) dx$. A quick trip to Wikipedia reveals that this is perfectly fine when $g$ is absolutely continuous, or when it has a continuous derivative, but may not be valid otherwise:
Edit: I didn't notice the word "smooth" in your question. In this light, the answer to your question is yes.
Also, MathWorld is probably a better reference: the two expressions are equal "if $f$ is continuous and $g'$ is Riemann integrable over the specified interval".