(In another question Nate Eldredge said I should ask this.)
Let $X$ be a Banach space, $X^\ast$ the dual space, and $B_{X^\ast}$ the unit ball of $X^\ast$. In the weak* topology for $X^\ast$, does one of these imply the other?
(a) $X^\ast$ is weak* separable
(b) $B_{X^\ast}$ is weak* separable
(b) implies (a):
Let $D$ be a countable dense set in $B_{X^\ast}$. Then $\overline{\bigcup_{n=1}^\infty nD} \supseteq \bigcup_{n=1}^\infty nB_{X^\ast} = X^\ast$ and $\bigcup_{n=1}^\infty nD$ is countable.
(a) does not imply (b):
provided the preprint Antonio Avilés, Grzegorz Plebanek, José Rodríguez, A weak* separable $C(K)^\ast$ space whose unit ball is not weak* separable (2011) is correct. I don't know if there are easier examples among less special spaces than C(K)*-spaces. If I interpret the introduction correctly, reference [14] could contain further examples.