Let's say I want to evaluate the following limit:
$$\lim_{(x,y) \to (0,0)} \frac{x^2 + y}{y}$$
and I choose the paths $x = 0$ (which gives me the limit equal to $1$) and I decide on the path $y = x$ also. By substituting $y = x$, does that allow me to use L'Hôpital?
$$\lim_{(x,y) \to (0,0)} \frac{x^2 + y}{y} = \lim_{x \to 0} \frac{x^2 + x}{x} = \lim_{x \to 0} \frac{2x+1}{1} = 1$$
Yes, you can use L'Hôpital though it is not necessary as you can just divide both the numerator and denominator by $x$.
Try to let $y=-x^2$ to prove that the limit doesn't exists.