The Lebesgue integral is defined as,
$$\int f \, d\mu = \text{sup}\, \Big\{ \sum_{z\in s(M)} z\,\mu \,\big(\text{pr_im}_s(\{z\})\big) \Big\}$$ or the supremum of the sum of the areas under the curve of the simple function $s$.
The question is, where in the definition of a simple function is it made clear that there is no overlap in the measures over which the sums are taken to prevent overcounting.
Graphically,
I guess the reason has to be in the definition of the domain of $z$: the measure $M$ as a topology space with no overlapping intervals?

The definition of a simple function includes the fact that a simple function is a function. A function has just one value for each argument.