Let G be a group of order $p^2q^2$ where $p > q$ are primes. If $|G| \ne 36$, show that G has exactly one Sylow p-subgroup.
Ok, I'm not exatly sure where to begin with this one. I know that we are using the Sylow theorems, but what confuses me is being given that $|G| \ne 36$. I am assuming that we will have to prove this for its different cases.
Let $n_p$ denote the number of Sylow p-subgroups of $G$. By the last Sylow theorem, $$ n_p | q^2, $$ so either $n_p = 1$, $n_p = q$, or $n_p = q^2$. If $n_p = q^2$, then by the first Sylow theorem, $$ q^2 \equiv 1 \pmod p \implies p | (q-1)(q+1). $$ Since $p > q$, this forces $p|(q+1)$, so $q=2$, $p=3$. But then $|G| = 36$, a contradiction.
I'll leave the $n_p = q$ case to you.