Let $K = \mathbb Q$ and $L = \mathbb( \sqrt[4] {3}, i)$. I see that $L \supset K$ is a an Galois extension. Also, after computations I've $[L : K] = 8$ (degree of $L$ over $K$ considered as a vector space).
Let $G = \text {Gal}(L/K)$.
How do I see that $\phi \in G$ is completely determined by $\phi\mathbb( \sqrt[4] {3})$ and $\phi(i)$ ?
I see that if $\mathbb {\sqrt[4] {3}}, i, 1$ is a basis for $L$ over $K$ then it must be true, since $x = a_1 \mathbb { \sqrt[4] {3} } + a_2 i + a_3 1$ for every $x \in L$ with $a_i \in K$, but this is not the case since the degree of $L$ over $K$ is $8$.
With $L=\Bbb Q(\sqrt[4]3)$ it's $[L:K]=4$ not $8$. But maybe you mean $L=\Bbb Q(\sqrt[4]3,i)$. In this last case the degree over $\Bbb Q$ is $8$ and this last one is a NORMAL extension of $\Bbb Q$ and this is necessary in order to consider Galois extensions: if $L$ is not normal (like $L=\Bbb Q(\sqrt[4]3)$) the Galois correspondance isn't guaranteed.
Said so, an automorphism $\phi\in G=\operatorname{Gal}(L|K)$ (with $L=\Bbb Q(\sqrt[4]3,i)$) is totally determined by knowing where $i$ and $\sqrt[4]3$ go because it's first of all an homomorphism which fixes pointwise $\Bbb Q$.
Explicitely, every element of $L$ is a linear combination of $1$ and powers of $i$ and $\sqrt[4]3$, with coefficients in $\Bbb Q$. To be more precise a base of $L$ over $K$ is given by $$ \{1,\sqrt[4]3,(\sqrt[4]3)^2,(\sqrt[4]3)^3,i,i\sqrt[4]3,i(\sqrt[4]3)^2,i(\sqrt[4]3)^3\} $$ hence by the properties of homomorphisms like $\phi(a_0i(\sqrt[4]3)^2)= \phi(a_0)\phi(i)\phi((\sqrt[4]3)^2)=a_0\phi(i)(\phi(\sqrt[4]3))^2$ ($a_0\in\Bbb Q$) you can see that the knowledge of $\phi(i)$ and $\phi(\sqrt[4]3)$, the automorphism is totally determined.