Let $I\subset \mathbb{R}$ be an open interval and let $f(x):I\to\mathbb{R}$ be a twice differentiable function in $a\in I$ s.a $f''(a)>0$.
Prove there exist $x_1,x_2\in I$, $x_1<a<x_2$ s.a:
$f'(a)=\frac{f(x_2)-f(x_1)}{x_2-x_1}$
Attempt: I tried to use MVT but I need to prove it for a specific $a$ and not just for some $x_1<c<x_2$
Note that $f''(a) > 0$. This means, that in a neighbourhood of $a$, $f'$ is increasing i.e. there is some $h > 0$ such that for all $0 < h' \leq h$, we have $f'(a-h') < f'(a) < f(a+h')$. Let $h' = \frac h2$, and define $g : [a-h',a]$ by $g(x) = \frac{f(x+ h')-f(x)}{h'}$.
Note that $g(a-h') = f'(c)$ for some $c \in (a-h',a)$ by the mean value theorem. Therefore, $g(a-h') = f'(c) < f'(a)$ since $a-h < a-h' <c < a$. Similarly, $g(a) = f'(d)$ for some $d \in (a,a+h')$, and again, $a+h > a+h'>c>a$, so that $f'(d) > f'(a)$. Therefore, $g(a) > f'(a) > g(a-h')$.
It follows by continuity of $g$ and the intermediate value theorem that there exists some $y \in (a-h',a)$ such that $g(y) = f'(a)$. But then, $g(y) = \frac{f(y+h') - f(y)}{(y+h')-y}$, where $y < a$ and $y+h' > a-h'+h' > a$. Therefore, put $x_1 = y$ and $x_2 = y+h'$ to get your result. Something stronger has been shown to hold, though.