Can anyone prove this (I'm very confident that it is correct) or have any idea how this can be handled:
$$ \lim_{n \rightarrow \infty} \frac{1}{n-1}\sum_{i=1}^{n-1} \frac{1}{(\alpha-1)(n-i) -1} \frac{n!}{(n-i-1)!} \frac{\Gamma(n-i+1-2/(\alpha-1))}{\Gamma(n+1-2/(\alpha-1))} = \frac{1}{\alpha-3}, $$
with $\alpha>3$.
Replacing the prefactor $1/(n-1)$ by $1/n$ does not change the limit. Using the change of variable $k=n-i$ and the shorthand $c=1/(\alpha-1)$, one gets that the $n$th quantity is $$ S_n=\frac{c\Gamma(n)}{\Gamma(n+1-2c)}\sum_{k=1}^{n-1}\frac{\Gamma(k+1-2c)}{(k-c)\Gamma(k)}. $$ The prefactor is equivalent to $cn^{2c-1}$ and, when $k\to\infty$, the $k$th term in the sum is equivalent to $k^{-2c}$, hence there are three regimes:
Finally, the result holds for every $\alpha\gt3$ (and not for every $\alpha\gt2$, as previously, erroneously, claimed in the question).