When I plotted the (normalized) Legendre polynoials, I couldn't help noticing that all the local maxima lay on a really nice curve:

What is the equation of the curve (and how can we arrive to that equation)?
When I plotted the (normalized) Legendre polynoials, I couldn't help noticing that all the local maxima lay on a really nice curve:

What is the equation of the curve (and how can we arrive to that equation)?
On
All the local maxima do not sit on the same "nice curve".
Under Wikipedia's normalisation with $\|P_n\|^2 = \frac{2}{2n+1}$ we can use Bonnet's recursion formula to get that
$$ (n+1)P_{n+1}(0) = - n P_{n-1}(0) $$
Since your "normalised" $\sqrt{\frac{2}{2n+1}}\tilde{P}_n = P_n$ we get that under your normalization
$$ \frac{n+1}{n} \sqrt{\frac{2n-1}{2n+3}} |\tilde{P}_{n+1}(0)| = |\tilde{P}_{n-1}(0)| $$
The multiplicative factor is
$$ \frac{n+1}{n} \sqrt{\frac{2n-1}{2n+3}} = \sqrt{ \frac{2n^3 + 3n^2 - 1}{2n^3 + 3n^2}} < 1 $$
Hence we have that the local maximum at $x = 0$ for $n = 0\pmod 4$ is strictly increasing, and hence cannot all belong to the same curve.
Perhaps the question you want to ask is: what is the smallest convex function defined on $(-1,1)$ that is greater than or equal to the normalised Legendre polynomials $\tilde{P}_{n}$?
On
Estimates of the form $$(1-x^2)^{1/4}|P_n(x)|<Cn^{-1/2}\tag{A1}$$ (here and in the sequel $-1\le x\le 1$) have a long history. Stiltjes obtained (A1) with unspecified $C$ in 1890. Gronwall (1913) and Fejer (1925) had explicit constants in (A1). Bernstein (1937) proved (A1) with sharp constant $C=\sqrt{2/\pi}$; his proof is presented in Orthogonal Polynomials by Szegő, section 7.3.
In terms of the $L^2$-normalized polynomials $\widetilde P_n=\sqrt{(2n+1)/2}\,P_n$, the sharp (Bernstein) form of (A1) becomes
$$(1-x^2)^{1/4}|\widetilde P_n(x)|\le \sqrt{\frac{2n+1}{\pi n}} \tag{A2}$$
where the right-hand side obviously approaches $\sqrt{2/\pi}$.
But the stronger and simpler inequality $$(1-x^2)^{1/4}|\widetilde P_n(x)| \le \sqrt{\frac{2}{\pi}} \tag{1}$$ is also true and is very tight. On the plot below, (A2) is in green while (1) is in red; the blue curve is $\widetilde P_9$.

Proof of (1). Let's return to original Legendre polynomial $P_n$. In terms of $P_n$ (1) takes the form $$(1-x^2)^{1/4}|P_n(x)|\le \frac{2}{\sqrt{\pi (2n+1)}} \tag2$$
Theorem 7.3.3 in Orthogonal Polynomials by Szegő (originally proved by Bernstein) is more precise than (A1). It says that $$(1-x^2)^{1/4}|P_n(x)| \le |P_n(0)|,\quad \text{if $n$ is even} \tag3$$ $$(1-x^2)^{1/4}|P_n(x)| < \frac{2}{\sqrt{(2n+1)^2+1}}|P_n'(0)|,\quad \text{if $n$ is odd} \tag4$$ Sketch of proof of (3)-(4). Let $u(\theta)=\sqrt{\sin\theta}P_n(\cos\theta)$ for $\theta\in [0,\pi/2]$. Check that $u''(\theta)+\varphi(\theta)u(\theta)=0$ where $\varphi(\theta)=(n+1/2)^2+1/(2\sin\theta)^2$. Show that $u^2+(u')^2/\varphi$ has positive derivative on the interval $(0,\pi/2)$. At $\theta=\pi/2$, either $u$ or $u'$ vanishes, and (3)-(4) follow. $\Box$
From the coefficients of Legendre polynomials we see that $$|P_{2k}(0)|=\frac{(2k-1)!!}{(2k)!!} \tag5 $$ $$|P_{2k+1}'(0)|=\frac{(2k+1)!!}{(2k)!!} \tag6 $$ The case of $n=2k$ turns out to be easier. A refined version of Wallis' product formula, proved by D.K. Kazarinoff in On Wallis' formula, states $$\frac{(2k-1)!!}{(2k)!!} = \frac{1}{\sqrt{\pi(n+\theta)}},\quad \frac14<\theta<\frac12 \tag7 $$ From (5) and (7) we have $$|P_{2k}(0)|<\frac{1}{\sqrt{\pi(k+1/4)}} = \frac{2}{\sqrt{\pi (4k+1)}} $$ which in view of (3) yields (2).
Instead of referring to Kazarinoff's paper one can prove directly that $$\left(\frac{(2k)!!}{(2k-1)!!}\right)^2\frac{4}{4k+1} \searrow \pi \tag8$$ Indeed, the limit is $\pi$ by Wallis' formula, and to show that the left hand side is decreasing, one has to check that $$ \left(\frac{2k+2}{2k+1}\right)^2\frac{4k+1}{4k+5}< 1 \tag9$$ Clearing the denominators in (9), one obtains $ (2k+2)^2 (4k+1)- (2k+1)^2(4k+5) = -1 <0$ which gives (9).
We can expect the case $n=2k+1$ to be harder, because (4) is not sharp, unlike (3).
And indeed, the combination of (4), (6), and (7) does not yield (2). Instead,
we can use a monotonicity fact similar to (8), though less elegant:
$$\left(\frac{(2k)!!}{(2k+1)!!}\right)^2\frac{(4k+3)^2+1}{4k+3} \searrow \pi \tag{10}$$
Indeed, the limit is $\pi$ by Wallis' formula, and to show that the left hand side is
decreasing, one has to check that
$$ \left(\frac{2k+2}{2k+3}\right)^2 \frac{(4k+7)^2+1}{4k+7}\frac{4k+3}{(4k+3)^2+1} < 1 \tag{11}$$
Clearing the denominators in (11), one obtains
$$ (2k+2)^2((4k+7)^2+1)(4k+3) -(2k+3)^2((4k+3)^2+1)(4k+7) = -(4k+5)^2-5<0$$
which gives (11).
From (10) it follows that $$ \frac{(2k+1)!!}{(2k)!!}\frac{2}{\sqrt{(4k+3)^2+1}} < \frac{2}{\sqrt{\pi(4k+3)}} \tag{12}$$ Combining (6) and (12) we obtain $$ \frac{2}{\sqrt{(4k+3)^2+1}}|P_{2k+1}'(0)| < \frac{2}{\sqrt{\pi(4k+3)}}$$ which in view of (4) yields (2). $\Box$
I claim that that curve is $$y=\pm \frac{\sqrt{2/\pi}}{ \sqrt[4]{1-x^2}}.$$ This argument will not be rigorous, and will cite a source I haven't fully understood.
Take a look at Whittaker and Watson, A course in Modern Analysis, p. 316. They write: $$P_n(\cos \theta) = \frac{4}{\pi} \frac{2 \cdot 4 \cdots (2n)}{3\cdot 5 \cdots (2n+1)} \left( \frac{\cos[(n+1/2) \theta - \pi/4]}{(2 \sin \theta)^{1/2}} + \frac{\cos[(n+3/2) \theta - 3\pi/4]}{2(2n+3) (2 \sin \theta)^{3/2}}+ \cdots \right)$$
This approximation seems to be very good in practice. In the picture below, the blue curve is $P_5(x) \sqrt{\sin(\cos^{-1} x)}$ and the red curve is $512/(63 \sqrt{11} \pi)*\cos((11/2) \cos^{-1}(x) - \pi/4)$. (These are the same normalizations user79365 is using in his post.)
I assume that, in more modern language, the authors are saying that this is an asymptotic series for $P_n(\cos \theta)$, valid on $(0, \pi)$. I have taken the liberties of applying some algebraic rearrangements, replacing their parameter $\phi$ by its definition and stopping the sum after two terms rather than the four they give. Also, they are using the normalization where $\int_{-1}^1 P_n^2 = 2/(2n+1)$, so you'd want to multiply by $\sqrt{(2n+1)/2}$.
For fixed $\theta$, that second term is bounded by $c/n$. The later terms (not displayed) die off even faster as $n$ grows. So $$\tilde{P}_n(\cos \theta)\approx \frac{4}{\pi} \sqrt{\frac{2n+1}{2}} \frac{2 \cdot 4 \cdots (2n)}{3\cdot 5 \cdots (2n+1)} \frac{\cos[(n+1/2) \theta - \pi/4]}{(2 \sin \theta)^{1/2}}$$ as $n \to \infty$. The $\sim$ over the $P$ indicates that I am now using your normalization. As long as $\theta/\pi$ is irrational, that $\cos$ term will swing between $1$ and $-1$, coming arbitrarily close to both ends. So $$\lim \sup_{n \to \infty} \tilde{P}_n(\cos \theta) = \lim_{n \to \infty} \frac{4}{\pi} \sqrt{\frac{2n+1}{2}} \frac{2 \cdot 4 \cdots (2n)}{3\cdot 5 \cdots (2n+1)} \frac{1}{(2 \sin \theta)^{1/2}}$$
Taking $1/\sqrt{\sin \theta} =1/\sqrt[4]{1-x^2}$ out of everything, we need to compute $$\lim_{n \to \infty} \frac{4}{\pi} \sqrt{\frac{2n+1}{2}} \frac{2 \cdot 4 \cdots (2n)}{3\cdot 5 \cdots (2n+1)} \frac{1}{\sqrt{2}}$$ This limit is similar to Wallis's product, and I think the second and third proofs on the Wikipedia page should be adaptable to evaluate it. I used the third proof, by Stirling's approximation: $$ \sqrt{2n+1} \frac{2 \cdot 4 \cdots (2n)}{3\cdot 5 \cdots (2n+1)} = \sqrt{2n+1} \frac{2^{2n} (n!)^2}{(2n+1)!} \approx \sqrt{2n+1} \frac{2^{2n} (n/e)^{2n} (2 \pi n)}{((2n+1)/e)^{2n+1} \sqrt{2 \pi (2n+1)}}$$ $$=\frac{2 \pi n \sqrt{2n+1}}{(1+1/2n)^{2n} \cdot (2n+1)/e \cdot \sqrt{2 \pi (2n+1)}}=\frac{e \sqrt{2 \pi}}{(2+1/n) (1+1/2n)^{2n}} \approx \frac{\sqrt{2 \pi}}{2}.$$
Putting back in the other constants gave the result I state above.
Remark It's fun to note that $$\int_{-1}^1 \left(\frac{\sqrt{2/\pi}}{\sqrt[4]{1-x^2}} \right)^2 dx = 2.$$ So $P_n^2$ is, on average, half the envelope above it.
Thanks to user79365 for providing the following image: The Legendre polynomials are in blue and the above curve is in red. It's also interesting to note the bunching up at values like $x=\pm 1/2$ and $x = 0$, when $\cos^{-1}(x)$ is a rational multiple of $\pi$.